Grand Challenges in CO2 Capture and Conversion

Document Type : Grand Challenges

Authors

Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran

Abstract

CO2 and its emission control is one of the main challenges in climate change mitigation. There are various methods for CO2 capture, including physical and chemical technologies such as chemical looping, post-combustion, pre-combustion, reduction and bio-technologies. Besides these methods, there are methods to convert CO2 into value-added products. However, both approaches face challenges that limit their commercialization. In this paper, the challenges of CO2 capture and conversion are examined and pros and cons of the methods to remove these obstacles are studied. Here, as a result, four main challenges in CO2 capture and conversion were presented: (1) energy consumption of existing technologies and some alternatives, (2) fixed and operational costs, (3) insufficient activity, sustainability and economics of existing catalysts or microorganisms for CO2 utilization and conversion, and (4) carbon footprint in existing technologies. Also, it was concluded that the need for more reliable life cycle assessment data for zero carbon footprint in existing and future CO2 capture and conversion technologies is one of the most important concerns that should be addressed in future studies to explore creative solutions for this issue.

Graphical Abstract

Grand Challenges in CO2 Capture and Conversion

Highlights

Ø CO2 as a major challenge in climate change.

Ø CO2 capture and conversion into value-added products.

Ø Energy, costs, effective catalysts, and carbon footprint as four main challenging issues.

 

Keywords

Main Subjects


Albo, J., Alvarez‐Guerra, M., Irabien, A., 2021. Electro‐, photo‐, and photoelectro‐chemical reduction of CO2, in: Teoh, W.Y., Urakawa, A., Ng, Y.H., Sit, P. (Eds.), Heterogeneous catalysts: Advanced design, characterization and applications. Vol. 1, Wiley-VCH GmbH, Weinheim, Germany, pp. 649-669. https://doi.org/10.1002/9783527813599.ch36
Bandehali, S., Ebadi Amooghin, A., Sanaeepur, H., Ahmadi, R., Fuoco, A., Jansen, J.C., Shirazian, S., 2021. Polymers of intrinsic microporosity and thermally rearranged polymer membranes for highly efficient gas separation. Sep. Purif. Technol. 278, 119513. https://doi.org/10.1016/j.seppur.2021.119513
Burkart, M.D., Hazari, N., Tway, C.L., Zeitler, E.L., 2019. Opportunities and challenges for catalysis in carbon dioxide utilization. ACS Catal. 9, 7937-7956. https://doi.org/10.1021/acscatal.9b02113
Castel, C., Bounaceur, R., Favre, E., 2021. Membrane processes for direct carbon dioxide capture from air: Possibilities and limitations. Front. Chem. Eng. 3, 668867. https://doi.org/10.3389/fceng.2021.668867
Centi, G., Perathoner, S., 2023. The chemical engineering aspects of CO2 capture, combined with its utilization. Curr. Opin. Chem. Eng. 39, 100879. https://doi.org/10.1016/j.coche.2022.100879
Chung, W., Lim, H., Lee, J.S., Al-Hunaidy, A.S., Imran, H., Jamal, A., Roh, K., Lee, J.H., 2022. Computer-aided identification and evaluation of technologies for sustainable carbon capture and utilization using a superstructure approach. J. CO2 Util. 61, 102032. https://doi.org/10.1016/j.jcou.2022.102032
De Ras, K., Van de Vijver, R., Galvita, V.V., Marin, G.B., Van Geem, K.M., 2019. Carbon capture and utilization in the steel industry: challenges and opportunities for chemical engineering. Curr. Opin. Chem. Eng. 26, 81-87. https://doi.org/10.1016/j.coche.2019.09.001
Ebadi Amooghin, A., Mashhadikhan, S., Sanaeepur, H., Moghadassi, A., Matsuura, T., Ramakrishna, S., 2019. Substantial breakthroughs on function-led design of advanced materials used in mixed matrix membranes (MMMs): A new horizon for efficient CO2 separation. Prog. Mater. Sci. 102, 222-295. https://doi.org/10.1016/j.pmatsci.2018.11.002
Ebadi Amooghin, A., Sanaeepur, H., Luque, R., Garcia, H., Chen, B., 2022. Fluorinated metal–organic frameworks for gas separation. Chem. Soc. Rev. 51, 7427-7508. https://doi.org/10.1039/D2CS00442A
Galán-Martín, Á., del Mar Contreras, M., Romero, I., Ruiz, E., Bueno-Rodríguez, S., Eliche-Quesada, D., Castro-Galiano, E., 2022. The potential role of olive groves to deliver carbon dioxide removal in a carbon-neutral Europe: Opportunities and challenges. Renew. Sust. Energ. Rev. 165, 112609. https://doi.org/10.1016/j.rser.2022.112609
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C.Y., Zhu, X., Wang, J., Huang, L., 2020. Industrial carbon dioxide capture and utilization: state of the art and future challenges. Chem. Soc. Rev. 49, 8584-8686. https://doi.org/10.1039/D0CS00025F
Gür, T.M., 2022. Carbon dioxide emissions, capture, storage and utilization: Review of materials, processes and technologies. Prog. Energy Combust. Sci. 89, 100965. https://doi.org/10.1016/j.pecs.2021.100965
Kumaravel, V., Bartlett, J., Pillai, S.C., 2020. Photoelectrochemical conversion of carbon dioxide (CO2) into fuels and value-added products. ACS Energy Let. 5, 486-519. https://doi.org/10.1021/acsenergylett.9b02585
Li, W., Wang, H., Jiang, X., Zhu, J., Liu, Z., Guo, X., Song, C., 2018. A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts. RSC Adv. 8, 7651-7669. https://doi.org/10.1039/C7RA13546G
Mashhadikhan, S., Ebadi Amooghin, A., Moghadassi, A., Sanaeepur, H., 2021. Functionalized filler/synthesized 6FDA-Durene high performance mixed matrix membrane for CO2 separation. J. Ind. Eng. Chem. 93, 482-494. https://doi.org/10.1016/j.jiec.2020.10.033
Nematolahi, K., Salehi, E., Ebadi Amooghin, A., Sanaeepur, H., 2022. CO2 separation of a novel Ultem‐based mixed matrix membrane incorporated with Ni2+‐exchanged zeolite X. Greenh. Gases: Sci. Technol. 12, 48-66. https://doi.org/10.1002/ghg.2122
Sandru, M., Sandru, E.M., Ingram, W.F., Deng, J., Stenstad, P.M., Deng, L., Spontak, R.J., 2022. An integrated materials approach to ultrapermeable and ultraselective CO2 polymer membranes. Science. 376, 90-94. https://doi.org/10.1126/science.abj9351
Sharifian, R., Wagterveld, R.M., Digdaya, I.A., Xiang, C., Vermaas, D.A., 2021. Electrochemical carbon dioxide capture to close the carbon cycle. Energy Environ. Sci. 14, 781-814. https://doi.org/10.1039/D0EE03382K
Spigarelli, B.P., Kawatra, S.K., 2013. Opportunities and challenges in carbon dioxide capture. J. CO2 Util. 1, 69-87. https://doi.org/10.1016/j.jcou.2013.03.002
U.S. Energy Information Administration, 2021. U.S. energy-related carbon dioxide emissions.      2021. https://www.eia.gov/environment/data
Valluri, S., Claremboux, V., Kawatra, S., 2022. Opportunities and challenges in CO2 utilization. J. Environ. Sci. 113, 322-344. https://doi.org/10.1016/j.jes.2021.05.043
Wei, K., Guan, H., Luo, Q., He, J., and S. Sun, 2022. Recent advances in CO2 capture and reduction. Nanoscale. 2022. 14: 11869-11891. https://doi.org/10.1039/D2NR02894H
Wilberforce, T., Olabi, A.G., Sayed, E.T., Elsaid, K., Abdelkareem, M.A., 2021. Progress in carbon capture technologies. Sci. Tot. Environ. 761, p.143203. https://doi.org/10.1016/j.scitotenv.2020.143203
Younas, M., Rezakazemi, M., Daud, M., Wazir, M.B., Ahmad, S., Ullah, N., Ramakrishna, S., 2020. Recent progress and remaining challenges in post-combustion CO2 capture using metal-organic frameworks (MOFs). Prog. Energ. Combust. Sci. 80, 100849. https://doi.org/10.1016/j.pecs.2020.100849